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Chapter 7

Principles of Nuclear Magnetic Resonance

핵 자기 공명(NMR): 개요
핵 자기 공명(NMR): 개요
Nuclear magnetic resonance (NMR) is a phenomenon exhibited by certain nuclei that can absorb characteristic radio frequency radiation under certain ...
원자핵 : 핵 스핀
원자핵 : 핵 스핀
All atomic particles possess an intrinsic angular momentum, or 'spin'. Electrons, protons, and neutrons each have a spin value of ½, although ...
원자핵: 핵 자기 모멘트(Atomic Nuclei: Nuclear Magnetic Moment)
원자핵: 핵 자기 모멘트(Atomic Nuclei: Nuclear Magnetic Moment)
All atomic nuclei are positively charged. When they have a nonzero spin, they behave like rotating charges. As a consequence of their charge and spin, ...
Atomic Nuclei: Nuclear Spin State 개요
Atomic Nuclei: Nuclear Spin State 개요
NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the ...
Atomic Nuclei: Nuclear Spin State 인구 분포
Atomic Nuclei: Nuclear Spin State 인구 분포
Near absolute zero temperatures, in the presence of a magnetic field, the majority of nuclei prefer the lower energy spin-up state to the higher energy ...
원자핵: 라모르 세차 운동 주파수
원자핵: 라모르 세차 운동 주파수
The earth's gravitational field produces a 'twisting force' perpendicular to the angular momentum of a spinning mass (such as a spinning top) ...
원자핵: 자기 공명
원자핵: 자기 공명
The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external ...
원자핵 : 핵 이완 과정
원자핵 : 핵 이완 과정
In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin ...
원자핵 : 핵 이완의 종류
원자핵 : 핵 이완의 종류
Relaxation in NMR systems is a first-order exponential decay and can occur by either spin–lattice or spin–spin mechanisms. Spin–lattice ...
NMR 분광계: 개요
NMR 분광계: 개요
NMR spectrometers consist of a strong magnet, a radiofrequency transmitter, and a detector attached to a computer console for recording spectra of samples ...
NMR 분광계: 무선 주파수 펄스 및 펄스 시퀀스
NMR 분광계: 무선 주파수 펄스 및 펄스 시퀀스
A pulse is a short burst of radio waves distributed over a range of frequencies that simultaneously excites all the nuclei in the sample. Upon passing a ...
NMR 분광계: 분해능 및 오류 수정
NMR 분광계: 분해능 및 오류 수정
When magnetic nuclei in a sample achieve resonance and undergo relaxation, the signal detected in NMR is an approximately exponential free induction ...
핵의 반자기 차폐: 국부 반자성 전류
핵의 반자기 차폐: 국부 반자성 전류
An applied magnetic field causes the electrons present in the molecule to circulate, setting up a local diamagnetic current within the molecule. The local ...
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