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Kapitel 16

Säure-Base- und Löslichkeitsgleichgewicht

Gemeinsamer Ioneneffekt
Gemeinsamer Ioneneffekt
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
Puffer
Puffer
A solution containing appreciable amounts of a weak conjugate acid-base pair is called a buffer solution, or a buffer. Buffer solutions resist a change in ...
Henderson-Hasselbalch-Gleichung
Henderson-Hasselbalch-Gleichung
The ionization-constant expression for a solution of a weak acid can be written as: Rearranging to solve for [H3O+] yields: Taking the negative ...
Berechnung von pH-Änderungen in einer Pufferlösung
Berechnung von pH-Änderungen in einer Pufferlösung
A buffer can prevent a sudden drop or increase in the pH of a solution after the addition of a strong acid or base up to its buffering capacity; however, ...
Wirksamkeit des Puffers
Wirksamkeit des Puffers
Buffer solutions do not have an unlimited capacity to keep the pH relatively constant . Instead, the ability of a buffer solution to resist changes in pH ...
Titrationsberechnungen: Starke Säure - Starke Base
Titrationsberechnungen: Starke Säure - Starke Base
Calculating pH for Titration Solutions: Strong Acid/Strong Base A titration is carried out for 25.00 mL of 0.100 M HCl (strong acid) with 0.100 M of a ...
Titrationsberechnungen: Schwache Säure - Starke Base
Titrationsberechnungen: Schwache Säure - Starke Base
Calculating pH for Titration Solutions: Weak Acid/Strong Base For the titration of 25.00 mL of 0.100 M CH3CO2H with 0.100 M NaOH, the reaction can be ...
Indikatoren
Indikatoren
Certain organic substances change color in dilute solution when the hydronium ion concentration reaches a particular value. For example, phenolphthalein ...
Titration einer polyprotischen Säure
Titration einer polyprotischen Säure
A polyprotic acid contains more than one ionizable hydrogen and undergoes a stepwise ionization process.  If the acid dissociation constants of the ...
Löslichkeits-Gleichgewichte
Löslichkeits-Gleichgewichte
Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many ...
Faktoren, die die Löslichkeit beeinflussen
Faktoren, die die Löslichkeit beeinflussen
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
Bildung komplexer Ionen
Bildung komplexer Ionen
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition ...
Ausfällung von Ionen
Ausfällung von Ionen
Predicting Precipitation The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is: It is important to realize ...
Qualitative Analyse
Qualitative Analyse
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a ...
Säure-Base-Titrationskurven
Säure-Base-Titrationskurven
A titration curve is a plot of some solution property versus the amount of added titrant. For acid-base titrations, solution pH is a useful property to ...
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