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Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction

32.9K Views

12:22 min

February 4th, 2013

DOI :

10.3791/4323-v

February 4th, 2013


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Samarium Diiodide

Hoofdstukken in deze video

0:05

Title

1:54

Synthesis of 0.1 M Samarium Diiodide

4:06

Samarium Barbier Reaction-hexamethylphosphoramide (HMPA) Addition

6:56

Samarium Barbier Reaction-Ni(acac)2 Catalyst

8:56

Results: The Impact of Additives on the Mechanism of the Samarium Barbier Reaction

11:51

Conclusion

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